Electron affinity of HO2 and HOx radicals
β Scribed by Benson, Sidney W.; Nangia, Prakash S.
- Book ID
- 127176524
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 274 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Replacement of N 2 by CO in H 2 + 02 + N 2 mixtures undergoing slow reaction at 500Β°C causes a marked increase in the reaction rate and a decrease in the induction period, expressed as the time to half maximum rate. A detailed interpretation using a computer treatment gives k24/klo 1/2 = 0.42 Β± 0.03
The rate-coefficients for the reactions HO2 + NO = HO + NO\* (1) and HO\* + HO = Hz0 + 0, (2) have been remeasured by laser magnetic resonance using an improved experimental arrangement. Values of kl = (6-9 f 0.6) X lO-12 cm3 molecule-' s-l and k2 = (5.8 -c 09) X 10-l cm3 molecule-' s-' (one standar