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Electrolytic Reductive Coupling. VI. 1 Aromatically Substituted Ethylenes 2

✍ Scribed by Baizer, Manuel M.; Anderson, James D.


Book ID
124073248
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
507 KB
Volume
30
Category
Article
ISSN
0022-3263

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The reduction of aromatic aldoxims and azines with Zn in the presence of MsOH or TiCl 4 afforded N,N%-unsubstituted 1,2-diamines in one-step. The reductive coupling with Zn-MsOH gave meso 1,2-diamines selectively, whereas dl 1,2-diamines were formed selectively by the reduction with Zn-TiCl 4 .