Electrolyte effects upon the polarographic reduction of alkyl halides in dimethyl sulfoxide
โ Scribed by Fry, Albert J.; Krieger, Richard L.
- Book ID
- 120040763
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 571 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Recent insights (1) in the remarkable solvent properties of dimethyl eulfoxida (DMSO), and our own interest in the chemistry of isopropcnyl ethers (2) led u8 to consider the poraibility of direot 0-alkylation of ethyl aoetoaoetate in that solvent. The connection i# that Kornblum'rr work (3) suggests
## Adam -The easier electrochemical reduction of uridme (I-/LLLtibofirranosylumcil) in dimethyl sulfoxide as compared to uracil (2, 4dihydroxypyrimidine) by ca. 0.1 V is exphcable on the basii of the electronwithdrawing effect of the ribose group. This effect and possible steric hindrance by the r