The electroinitiated polymerization of styrene in tetrabutylammonium perchlorate-dimethylsulphate solutions has been investigated. Polystyrene of low molecular weight is formed cationically through a direct monomer oxidation to the radical cation. Kinetic as well as mechanistic considerations for th
Electroinitiated polymerization of styrene in propylene carbonate
โ Scribed by Pistoia, Gianfranco
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1972
- Tongue
- English
- Weight
- 227 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0449-2986
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract A constant controlled current was passed through a solution of styrene in methylene chloride containing a tetraalkylammonium salt as supporting electrolyte. Reproducible rates of polymerization were initiated by the electrochemical techniques employed and the kinetics of the reaction we
The electroinitiated polymerization of 2-ethylhexylacrylate in dimethylfonnamide in the presence of tetrabutylammoniumiodide was investigated at 288-314 K, with graphitized monofibers being used as a cathode. Electron microscopy showed that the surface of a carbon fiber is characterized by considera