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Electrogenerated chemiluminescence with solvated electrons in hexamethylphosphoroamide (HMPA)

✍ Scribed by Kingo Itaya; Mikio Kawai; Shinobu Toshima

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
432 KB
Volume
42
Category
Article
ISSN
0009-2614

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The ratc of disappearance of solvated electrons by reaction with fluorobcnzcne in ammonia is acce!erated by smal1 conccntrations of methanol; it also bas a "negative activation energy" depending on the methanol concentration. The kinetic dota suggest an csothermic electron attachment-detachment equi