Electrode reactions of 2,2,6,6-tetramethylpiperidinenitroxide (TMPNO) and di-tertbutytnitroxide (DTBNO) at platinum in acetonitrile solution were investigated by means of linear sweep voltammetry and controlled potential coulometry. In the case of TMPNO, the voltammetric results were satisfied with
Electrode reaction mechanisms of platinum isocyanide complexes in acetonitrile solutions
β Scribed by Katsuo Takahashi; Yasuhiro Yamamoto; Kiyoshi Matsuda; Hiroshi Yamazaki
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 373 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
Electrochemical reaction properties of platinum(I1) aryl isocyanide complexes were investigated to determine preparative conditions of electroreduction and to analyse formation mechanisms of low-valent di-and tri-platinum complexes. Polarographic and chronoamperometric measurements were carried out for the analysis of reaction properties of Pt-complexes, PtCl,L, and Pt2CI,L4 (L means 2,4-t-Bu,
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Electrode reaction of 2,2,6,6-tetramethylpiperidine-nitroxide (TMPNO) cation at platinum in acetonitrile containing anhydrous hydrogep chloride was investigated by means of linear sweep voltammetry, electric conductivity measurement and esr spectrum, TMPNO cation is reversibly reduced to TMPNO radic
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