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Electrode reaction mechanisms of platinum isocyanide complexes in acetonitrile solutions

✍ Scribed by Katsuo Takahashi; Yasuhiro Yamamoto; Kiyoshi Matsuda; Hiroshi Yamazaki


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
373 KB
Volume
33
Category
Article
ISSN
0013-4686

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✦ Synopsis


Electrochemical reaction properties of platinum(I1) aryl isocyanide complexes were investigated to determine preparative conditions of electroreduction and to analyse formation mechanisms of low-valent di-and tri-platinum complexes. Polarographic and chronoamperometric measurements were carried out for the analysis of reaction properties of Pt-complexes, PtCl,L, and Pt2CI,L4 (L means 2,4-t-Bu,


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