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Electrochemistry of the trinuclear aqua Mo3IV and Mo3III ions in acidic media

โœ Scribed by Paffett, Mark T.; Anson, Fred C.


Book ID
126042884
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
1008 KB
Volume
22
Category
Article
ISSN
0020-1669

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involved are summarized in Table 111. In Hg4(A~F6)2, however, the interaction of the Hg: + ion with the AsFC anion in a direction approximately collinear with the terminal Hg-Hg bonds is replaced by the intercation Hga-Hg interaction at 124O to the terminal Hg-Hg bond and several weak Hg-F contacts

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The reaction of trinuclear MO(N), incomplete cuboidal complexes [Mo,S,(H,O),]~+, [Mo,OS,(H,O),]~+ and Fro,W,W,W4+ with BH.,-in aqueous HCl solutions results in the conversion of core ligands A-S to h-0. In combination with Dowex cation-exchange chromatography the procedure can be used on a preparati