Electrochemistry of hexacoordinate silicon(IV) porphyrin complexes
β Scribed by Carrie R. Lorenz; Howard D. Dewald; Frederick R. Lemke
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 462 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1040-0397
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## Abstract A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO)~4~. All the compounds synthesized were structurally characterized by singleβcrystal Xβray diffraction and/or solidβstate NMR spectroscopy. In additio
A number of octaphenoxyphthalocyaninato silicon complexes containing a variety of axial ligands, represented by ( OPh )~8~ PcSi ( X )~2~ (where X = chloro 3, hydroxy 4, (4-carboxybenzene) acetato 5, isonicatinato 6, propionato 7, nitrophenoxy 8 and dimethylaminoxy 9) have been synthesized using a co