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Electrochemistry and [60]fullerene displacement reactions of (dihapto-[60]fullerene) pentacarbonyl metal(0) (M = Cr, Mo, W)

✍ Scribed by Igart?a-Nieves, Elvin; Ocasio-Delgado, Yessenia; Torres-Castillo, Mar?a D. L. A.; Rivera-Betancourt, Omar; Rivera-Pag?n, Jos? A.; Rodriguez, Diana; L?pez, Gustavo E.; Cort?s-Figueroa, Jos? E.

Book ID: 118280726
Publisher: Royal Society of Chemistry
Year: 2007
Tongue: English
Weight: 188 KB
Volume: 13
Category: Article
ISSN: 1477-9226
DOI: 10.1039/b618260g

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## Abstract This paper reports on several new optically active organometallic [60]fullerene complexes that contain a chiral (+)‐DIOP or (−)‐DIOP ligand [DIOP = 2,3‐__O__,__O′__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphanyl)butane]. The Mo/W complexes __mer__‐[(η^2^‐C~60~)M(CO)~3~{(−)‐DIOP