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Electrochemically assisted catalyst for enzymatic glucose oxidation

✍ Scribed by P. Gros; A. Bergel; M. Comtat


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
530 KB
Volume
51
Category
Article
ISSN
0009-2509

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✦ Synopsis


A catalyst was made by entrapping glucose oxidase in a polymeric film deposited on an electrode surface. Its efficiency was studied by measuring the transformation of glucose by oxygen into gluconic acid. A numerical model was elaborated and validated with respect to experimental data. The electrochemical step affected the enzymatic catalysis in two ways: the reactant oxygen was regenerated, and the product, hydrogen peroxide which is a glucose oxidase inhibitor, was consumed. By monitoring these two concentrations, the electrochemical assistance significantly enhanced catalyst efficiency.


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