Abstract
Titanium‐supported nanoscale flaky nickel electrode (nanoNi/Ti) was prepared by a hydrothermal process using hydrazine hydrate as a reduction agent. Its electrocatalytic activity as an electrocatalyst for the electrooxidation of glucose was evaluated in alkaline solutions using cyclic voltammetry (CV), chronoamperometric responses (CA) and electrochemical impedance spectra (EIS). The nanoNi/Ti electrode exhibits significantly high current density of glucose oxidation. A high catalytic rate constant of 1.67×10^6^ cm^3^ mol^−1^ s^−1^ was calculated from amperometric responses on the nanoNi/Ti electrode. Low charge transfer resistances on the nanoNi/Ti in 0.5 M NaOH containing various concentrations of glucose were obtained according to the analysis for EIS. Furthermore, amperometric data show a linear dependence of the current density for glucose oxidation upon glucose concentration in the range of 0.05–0.6 mM with a sensitivity of 7.32 mA cm^−2^ mM^−1^. A detection limit of 0.0012 mM (1.2 μM) M glucose was found. Results show that the prepared nanoNi/Ti electrode presents high electrocatalytic activity for glucose oxidation.