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Electrochemical synthesis of cyclo[8]pyrrole

✍ Scribed by Bucher, Christophe; Devillers, Charles H.; Moutet, Jean-Claude; P?caut, Jacques; Sessler, Jonathan L.


Book ID
120173803
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
373 KB
Volume
37
Category
Article
ISSN
1359-7345

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Electrochemical Syntheses of Cyclo[n]pyr
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## Abstract Cyclo[8]pyrrole was obtained efficiently when 3,3′,4,4′‐tetraethylbipyrrole was subjected to bulk electrolysis, with yields spanning a range from close to 0 % with tetra‐__n__‐butylammonium fluoride as the electrolyte, to almost 70 % when tetra‐__n__‐butylammonium hydrogensulfate was us

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## Cyclo[8] pyrrole (1), although lacking bridging meso carbon atoms, may be considered as a larger analogue of porphyrin (2) in that it is flat and aromatic (see Scheme 1). [1] For this reason, we have been interested in exploring the chemical behavior of cyclo [8]pyrrole and contrasting it to th