Electrochemical synthesis of cyclo[8]pyrrole
✍ Scribed by Bucher, Christophe; Devillers, Charles H.; Moutet, Jean-Claude; P?caut, Jacques; Sessler, Jonathan L.
- Book ID
- 120173803
- Publisher
- Royal Society of Chemistry
- Year
- 2006
- Tongue
- English
- Weight
- 373 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1359-7345
- DOI
- 10.1039/B606998C
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Cyclo[8]pyrrole was obtained efficiently when 3,3′,4,4′‐tetraethylbipyrrole was subjected to bulk electrolysis, with yields spanning a range from close to 0 % with tetra‐__n__‐butylammonium fluoride as the electrolyte, to almost 70 % when tetra‐__n__‐butylammonium hydrogensulfate was us
## Cyclo[8] pyrrole (1), although lacking bridging meso carbon atoms, may be considered as a larger analogue of porphyrin (2) in that it is flat and aromatic (see Scheme 1). [1] For this reason, we have been interested in exploring the chemical behavior of cyclo [8]pyrrole and contrasting it to th