Electrochemical synthesis of cis-3,4-bis(2,2,2-trifluoroethyl)pyrrolidine
β Scribed by Norbert Muller
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 316 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Michael-addition of nitromethane anion to 5-ylidene-1,3-dioxane-4-ones 2 gives high yields of 5-(13-nitroalkyl)-l,3-dioxane-4-ones 3 and 4 with a preponderance of 3 (reattack). Hydrogenation of the products in the presence of Raney-Ni affords optically active 4-substituted cis-3-(o~-hydroxyethyl)-py
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