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cis-Selective Synthesis of 2,5-Disubstituted Pyrrolidines.

โœ Scribed by Syed Raziullah Hussaini; Mark G. Moloney

Publisher
John Wiley and Sons
Year
2004
Weight
87 KB
Volume
35
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Selective One-Step
ChemInform Abstract: Selective One-Step Synthesis of Enantiopure cis-2,5-Disubstituted Pyrrolidines or cis-3,6-Disubstituted Piperidines from the (2R,2โ€ฒR)-(1,2-Ethanediyl)bis-aziridine.
โœ S. FORT; I. MCCORT; A. DUREAULT; J.-C. DEPEZAY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Selective One-Step Synthesis of Enantiopure cis-2,5-Disubstituted Pyrrolidines or cis-3,6-Disubstituted Piperidines from the (2R,2'R)-(1,2-Ethanediyl)bis-aziridine. -Chromatographic purification of the optically active bis-aziridine (I) results in a 5-exo-tet aminocyclization to the cis-2,5-disubst