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Electrochemical synthesis and a redetermination of Ni(acac)2(H2O)2·H2O

✍ Scribed by Zhou, Xing-Fu ;Han, Ai-Jie ;Chu, Dao-Bao ;Huang, Zi-Xiang

Publisher: International Union of Crystallography
Year: 2001
Tongue: English
Weight: 302 KB
Volume: 57
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536801016208

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✦ Synopsis

The title complex, bis(acetylacetonato)diaquanickel(II) monohydrate, [Ni(C 5 H 7 O 2 ) 2 (H 2 O) 2 )]ÁH 2 O, was easily synthesized in high yield by electrochemical dissolution of nickel metal in an acetylacetone and ethanol solution via direct hydrolysis of the electrolyte solution at a temperature of 333 K. The crystal structure shows octahedral coordination of nickel with two trans aqua ligands. An uncoordinated water molecule engages in hydrogen bonding.

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