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Electrochemical reduction of gallium(III) in non-aqueous solvents, assisted by 2,2′-bipyridine

✍ Scribed by Pablo Cofre; Gaston East; Claudia Aguirre


Book ID
118996100
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
864 KB
Volume
39
Category
Article
ISSN
0039-9140

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The kinetics of the oxidation of glutathione by diaquatetrakis(2,2'-bipyridine)-#-oxo diruthenium(III) ion in aqueous HC104 have been investigated. The reaction obeys the empirical rate law: where k=7.42\_+0.40• -1 at 25.5~ [H+]= 0.005-0.05 M and I = 1.0 M (LiC104). Free radicals are important in