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Electrochemical reduction of carbon dioxide catalyzed by cofacial dinuclear metalloporphyrin

✍ Scribed by Enoki, Osamu; Imaoka, Takane; Yamamoto, Kimihisa


Book ID
120605141
Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
401 KB
Volume
204
Category
Article
ISSN
1022-1360

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Electrochemical reduction of benzyl chlo
✍ Frank C. J. M. van Veggel; Willem Verboom; David N. Reinhoudt; Martinus Bos πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 267 KB

## Abstract The co‐complexed Ba^2+^ cation in the hetero‐dinuclear complex 1 stabilizes the carbon‐nickel bond that is formed in the reductive coupling of benzyl chloride and 1; the β€œPhCH~2~ο£ΏNi^II^/Ba^2+^” intermediate reacts with CO~2~ or acetic anhydride.