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Electrochemical reduction mechanism of tetrafluoro(triphenyl-phosphineiminato)tungsten(VI)

✍ Scribed by T. Tojo; D. Westhoff; H.W. Roesky


Book ID
103181847
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
47 KB
Volume
35
Category
Article
ISSN
0022-1139

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The reduction mechanism of uranium(VI)-cupferron was studied by different electrochemical techniques such as stripping voltammetry and cyctic vottammetry. it is proposed that the U(M) ions in the form of adsorbed complexes with cupferron are reduced at -0.46 V to U(V). The further reduction to U(III