Electrochemical reduction mechanism of EDTA complexes of U4+ and UO2+2 at HMDE in aqueous solution
โ Scribed by Ki-Suk Jung; Se Chul Sohn; Yeong Keong Ha; Tae Yoon Eom; Sock Sung Yun
- Publisher
- Elsevier Science
- Year
- 1991
- Weight
- 685 KB
- Volume
- 315
- Category
- Article
- ISSN
- 0022-0728
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The pohuographic reduction of 2,4,6trinitro diphenylamine was found to give three waves of nearly equal height in all pH regions in buffered solutions and also in unbuffered methanol-water mixtures. The waves were shown to be diffusion-controlled and irreversible on the basis of the usual criteria.
In acetonitrile containing tetraethyhunmonium perchlorate, cyclic voltammograms for the reduction of 2,4,6-trimethylbenxoyl chloride at glassy carbon and hanging mercury drop electrodes exhibit five and four cathodic waves, respectively. At potentials corresponding to the first wave, cleavage of the