Ahstraet-Wf-assembled monolayers of the alkanethiols having OH, COOH and NH, terminal group were formed on a gold electrode via a sulfur attachment. The effects of their terminal groups on the redox responses of Fe&N):-, Ru(NH&+ and l,l'-ferrocenedimethanol (FcDM') aqueous solutions were investigate
✦ LIBER ✦
Electrochemical properties of the gold electrode modified with mixed monolayer assembly. The effect of a polar head group on the kinetics of the Fe(CN)3−6/Fe(CN)4−6 reaction
✍ Scribed by Kô Takehara; Yasushi Ide
- Publisher
- Elsevier
- Year
- 1992
- Tongue
- English
- Weight
- 542 KB
- Volume
- 342
- Category
- Article
- ISSN
- 1572-6657
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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__