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Effects of the solution pH on the electrochemical behaviour of Ru(bpy)2+3 and Fe(CN)3−6 ions at a clay-modified electrode

✍ Scribed by Hiroshi Inoue; Shigeo Hage; Chiaki Iwakura; Hiroshi Yoneyama


Publisher
Elsevier Science
Year
1988
Weight
686 KB
Volume
249
Category
Article
ISSN
0022-0728

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__