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Electrochemical properties and photoelectrochemical response of vacuum-deposited poly(p-phenylene) thin films

✍ Scribed by Kohichi Miyashita; Masao Kaneko


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
362 KB
Volume
7
Category
Article
ISSN
1042-7147

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✦ Synopsis


The electrochemical properties of a poly(p-phenylene) (PPP) thin film prepared by vacuum deposition were investigated by cyclic voltammetry in organic and aqueous media with a lithium perchlorate electrolyte. The PPP thin film was able to undergo both n-doping and p-doping reversibly. In an aqueous medium, the cyclic voltammograms indicated the characteristic loop in a potential sweep. The loop was ascribed to the charge transfer on the PPP film surface and to an accumullafion effect of the charge in the PPP film. A photocurrent was observed at the PPP film under UV light irradiation.


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