Electrochemical polymerization of acenaphthylene in nitrobenzene and nitromethane
β Scribed by Yasuo Kikuchi; Akihiro Matsuno
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 170 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0021-8995
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The polymerizations of indene and acenaphthylene by TiC14-CCI3CO2H in dichloromethane take place in two stages, viz. a fast initial reaction followed by a slow stationary-state process. A mechanism involving the relaxation of active centres created by fast initiation to an equilibrium mixture of act
The electrochemical reduction of five conjugated and non-conjugated nitriles, CH3CH--CHCN (la, trans/cis = 62/38%); CH3CH2CH--CHCN (lb, cis); CH3CH~CHCH2CN (lc, trans), CH3CH~C(CH3)CN (ld) and CH2~CHCH(CH3)CN (le) have been investigated in acetonitrile, and of two derivatives, la and CHz--C(CH3)CN (
Spin-lattice relaxation measurements of composite systems with different monomer-to polymer ratios are consistent with the phase diagram described previously. Relaxation curve of the system with monomer content higher than ML., shows behaviour different from those for systems of higher polymer conte