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Electrochemical oxidation of nitrite: Kinetic, mechanistic and analytical study by square wave voltammetry

โœ Scribed by Ying Wang; Eduardo Laborda; Richard G. Compton


Book ID
116637557
Publisher
Elsevier
Year
2012
Tongue
English
Weight
550 KB
Volume
670
Category
Article
ISSN
1572-6657

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Kinetic and mechanistic studies on the o
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The kinetics of oxidation of nitrite to nitrate by peroxornonophosphoric acid in aqueous acid medium have been studied. The observed monotonic fall in rate with increasing pH of the medium has been rationalized on the basis of proton-dissociation equilibria of the substrate as well as the oxidant sp

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The voltammeric behavior of the herbicide cyclosulfamuron has been studied by square wave stripping voltammetry (SWSV). Cyclosulfamuron was reduced on a static mercury drop electrode (SMDE) and gave a well-defined peak in the pH range of 3.0-7.0. The peak potential (E p ) shifts to a more negative p