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Electrochemical obtention of cis- and trans-3,6-dimethoxy-3,6-dimethyl-1,4-cyclohexadienes

✍ Scribed by Barba, Fructuoso; Guirado, Antonio; Barba, Isidoro

Book ID: 126124287
Publisher: American Chemical Society
Year: 1984
Tongue: English
Weight: 427 KB
Volume: 49
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00190a031

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Die Frage nach dem Mechanismus der Oxidation von ( 1 ) zu ( 2 ) ist noch offen. Wir versuchenzu klaren, ob zunachst ein 0-Komplex entsteht, oder ob die Reaktion iiber ein Radikalkation verlauft. Der Umsetzung von ( 1 ) rnit Antimonpentafluorid in S02CIF, die ebenfalls zu ( 2 ) fiihrt, diirfte ein Ra