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Electrochemical generation of a dimeric macrocyclic complex

โœ Scribed by McElroy, Francis C.; Dabrowiak, James C.


Book ID
121506256
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
242 KB
Volume
98
Category
Article
ISSN
0002-7863

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Catalytic Generation of Hydrogen with Ti
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## Abstract Hydrogen evolution from acidic aqueous solutions of Ti^III^citrate is strongly catalyzed by Co(dmgBF~2~)~2~. The reaction generates an intermediate with maximum absorbance at 770 nm. The slow disappearance of this intermediate takes place simultaneously with the generation of H~2~ in a