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Photoinduced dimerization of macrocyclic complexes mediated by a metal-assisted oxidation of the macrocycle

✍ Scribed by Ferraudi, G.; Muralidharan, S.

Book ID
126115661
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
643 KB
Volume
20
Category
Article
ISSN
0020-1669

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✍ Philipp Schultz-Grunow; Thomas A. Kaden πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 254 KB πŸ‘ 1 views

## Abstract The complexation kinetics of the two macrocycles **1** and **2** with Co^2+^, Ni^2+^, Cu^2+^ and Zn^2+^ have been measured by pH‐stat techniques. The rates are first order in metal and ligand concentration and depend upon the pH. This results from the different reactivities of the vario