The diffusion coefficient ofthe perhydroxyl ion (HO;) was dctermincd in 4.5 M LiOH supporting electrolyte. Over the range of concentration 0.2-0.8 M H,O, it was found to be independent ofconcentration and had a value of 5 \* 0.2 x 10m6 cm'/s at 293 K. The experimental data were obtained cbronoampero
Electrochemical determination of the lithium ion diffusion coefficient in TiS2
โ Scribed by Anthony J. Vaccaro; T. Palanisamy; R.L. Kerr; J.T. Maloy
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 385 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0167-2738
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The diffusion coefficient of OH -in LiOH solution was found to be 6.8 x lo-s cm2/s at 298 K at infinite dilution. The experimental technique utilized a rde at which the limiting current for 0, evolution was measured. Because the O2 gas bubbles impact on convection at the electrode, the Levich equati
The investigation of the kinetics of the vapour phase oxidation of furfural over vanadium catalyst reported earlier [l] has been extended to establish the mechanism of this reaction. Langmuir-Hinshelwood, Rideal and redox mechanisms are employed for the elucidation of the mechanism of this reaction.