Electrochemical dealkylation of aliphatic amines
โ Scribed by Smith, Paul J.; Mann, Charles K.
- Book ID
- 120209395
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 753 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Phenyl chlorothionoformate reacts rapidly with aliphatic amines at 20ยฐC to give a thiourethane and an alkyl chloride. The urethanes are readily converted to the secondary amine salt by reaction with dimethyl sulfate, followed by hydrolysis with water. Rates of reaction, and alkyl group cleavage sele
In acetonitrile containing water aliphatic amines are smoothly dealkylated electrochemically at platinum to give an amine of lower order and an aldehyde. When the oxidation of either tri-n-propylamine or di-n-propylamine was carried out in rigorously dried acetonitrile containing concentration five