Electrochemical cleavage of the nitrogen-nitrogen bond in hydrazido(2-) complexes of molybdenum: Formation of ammonia
✍ Scribed by T. Adrian George; David N. Kurk; Jody Redepenning
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 280 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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📜 SIMILAR VOLUMES
By treatment with Li metal in THF at room temperature the three isomeric N,N-dimethylaminobiphenyls and NJ-dimethyl-2,6-diphenylanilineunderwent 100% regioselective reductive cleavage of the aryl-N bond, affording biphenyl and me&-terphenyl, respectively, in various yields.
## Abstract The metal–nitrogen bond in six‐coordinate complexes [ML^1^Cl]^+^ (M = Co, Ni, Cu or Zn) of (pyridyloxy)cyclophosphazene, five‐coordinate complexes [ML^1^Cl~2~] (M = Cu or Zn) of green‐[NiL^1^Cl~2~], and dimetallic complexes [L^2^(CuCl~2~)~2~], [L^3^(CuCl)~2~]^2+^ and [L^3^(CuCl~2~)~2~]