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Electrochemical behaviour of tetraazamacrocyclic nickel(II) complexes functionalized with crown ethers

✍ Scribed by Joanna Taraszewska; Katarzyna Zięba; Jarosław Kowalski; Bohdan Korybut-Daszkiewicz

Book ID
108119160
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
809 KB
Volume
53
Category
Article
ISSN
0013-4686

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Nickel(II) Tetraazamacrocyclic Complexes
Nickel(II) Tetraazamacrocyclic Complexes with Two Pendant Amino Groups: Electrochemical and Kinetic Studies
✍ Bohdan Korybut-Daszkiewicz; Joanna Taraszewska; Bohdan Kamieński 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 349 KB 👁 1 views

7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecanenickel(II) and -4,11-dienenickel(II) complexes (1-4) were studied by cyclic voltammetry. The thermodynamic stability of Ni III was the greatest in complex 4 with a trans configuration of the pendant amino groups. On acidification, the Ni II /Ni