Effects of axial anions and solvent on the redox behaviour of nickel complexes with C-functionalized tetraazamacrocycles
β Scribed by C. Boudon; J.-P. Gisselbrecht; M. Gross; T. Benabdallah; R. Guglielmetti
- Publisher
- Elsevier
- Year
- 1993
- Tongue
- English
- Weight
- 853 KB
- Volume
- 345
- Category
- Article
- ISSN
- 1572-6657
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The stopped-flow technique has been used to study the effect of cationic (CTAN), nonionic (Triton X-loo), and anionic (SDS) micelles on the rate of the reaction between nickel(I1) ion and the ligand pyridine-2-azo-p-dimethylaniline (PADA) at 20.0"C and ionic strength 0.03 mol dm-3. The complex forma
## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0β50 (v/v) % MeOH) at 15.0β35.0Β°C and I = 0.10 mol dm^β3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ Β· CoOCOCO~2~Ni]^3+^ in wh