Electrochemical Behavior of Aromatic N-Nitrosohydroxylamines
โ Scribed by Elving, Philip J.; Olson, Edward C.
- Book ID
- 127071176
- Publisher
- American Chemical Society
- Year
- 1957
- Tongue
- English
- Weight
- 938 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The major products of the hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines (3) are the denitrosated parent hydroxylamines (6); under mom forcing conditions, products of the further hydrolysis of 6 are obtained. Acetolysis in acetic acid gives the benzyl acetates derived from both N-and 0-substitue
SUM!.4ARY: The action 06 N,N-dibenzy1tibamoyL ckeohide (21 on -the bodium da.& 06 N-niattobo-hy&oxy&minti (11 in dhy actiome at he&&ix .&&4 ti pmduc& whobe ,(otmati\_on may be trationaL&d in &amb 06 canbamoylatin aR e&heh oxygen 06 the bididen&zte N-tiobohy&oxy,kmi.mb.
Several novel N-substituted N-nitrosohydroxylamines were synthesized. They all inhibited mushroom tyrosinase, but the type of inhibition was different depending on the substituent. Some N-(mono- or dihydroxybenzyl)-N-nitrosohydroxylamines exhibited uncompetitive inhibition with respect to L-dopa. Am