Electrochemical Behavior of Alkali Metal Alcoholates (Alcoxides) on Mercury
✍ Scribed by Michael Heyrovský
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 91 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1040-0397
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The electrochemistry of Mo(VI) in sulfuric acid solutions has been investigated at mercury and glassy carbon surfaces, the adsorption of Mo(VI) and electrogenerated products being evident at mercury electrodes. The adsorption phenomenon severely complicates the electrochemical behavior and depressed
The electrochemical oxidation of the alkali‐metal ions Cs^⊕^, Rb^⊕^, K^⊕^, and Na^⊕^ appears to occur in liquid sulfur dioxide, but only at about + 4.7 V vs. SCE, as shown by studies on their AsF and PF salts for which other sources of the observed oxidation waves could be excluded. No evidence for