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Electrochemical and corrosion behaviour of iron in acetonitrile solutions

✍ Scribed by C. Farina; G. Faita; B. Bazzoni

Book ID
115846154
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
416 KB
Volume
20
Category
Article
ISSN
0010-938X

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km dissolution as well as hydrogen evolution was studied in HCI and HBr acetonitrile solutions in a concentration range between 2.8 x IO-' M and 9.8 x 10m4 M. Halide concentration was changed by adding lithium halide to some of the previous solutions. Measurements were performed at 00Β°C. Current ef

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Impedance spectroscopy is used in conjunction with polarization measurements in order to interpret the mechanism of acctonitrile adsorption on iron electrodes in the pH=2.5-1.0 interval. The results suggest that at least two adsorbed intermediates participate in the reaction sequence. Since the time