## Abstract This paper describes electrochemical behavior of laccase from the fungus __Trametes versicolor.__ The issues related to discrimination of the redox potentials corresponding to copper centers T1 and T2/T3 in the active site and possible mechanism of intramolecular electron transfer have
✦ LIBER ✦
Electrochemical and Computational Studies on Intramolecular Dissociative Electron Transfer in β-Peptides
✍ Scribed by Yu, Jingxian; Huang, David M.; Shapter, Joe G.; Abell, Andrew D.
- Book ID
- 125499721
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 513 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1932-7447
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## Abstract The electron and proton transfer in phenol‐imidazole‐base systems (base = NH~2~^−^ or OH^−^) were investigated by density‐functional theory calculations. In particular, the role of bridge imidazole on the electron and proton transfer was discussed in comparison with the phenol‐base syst