Kinetics and mechanism of the reductions
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Adedayo B. Adegboro; J.Folorunso Ojo; Olusegun Olubuyide; Oluyemisi T. Sheyin
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Article
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1987
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Elsevier Science
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English
โ 432 KB
The reductions of azido-and isothiocyanato-pentacyanocobaltate(II1) by hexaammine-and aquapentaammineruthenium(I1) have been investigated in aqueous solution at I = 0.20 mol dmm3 (LiCl) and the values at 25 "C of the rate constants (dm3 mol-' s-l) are ky = 1.71 and kNCs = 0.8 1 for the Ru(NH~)~~+ re