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Electrochemical and chemical aspects of ruthenium(II) and (III) ammines in basic solution: The role of the ruthenium(IV) species

โœ Scribed by Metzker, Gustavo; de Aguiar, Inara; Martins, Silvia C.; Schultz, Mario S.; Vasconcellos, Luiz C.G.; Franco, Douglas W.


Book ID
122219299
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
681 KB
Volume
416
Category
Article
ISSN
0020-1693

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Kinetics and mechanism of the reductions
โœ Adedayo B. Adegboro; J.Folorunso Ojo; Olusegun Olubuyide; Oluyemisi T. Sheyin ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 432 KB

The reductions of azido-and isothiocyanato-pentacyanocobaltate(II1) by hexaammine-and aquapentaammineruthenium(I1) have been investigated in aqueous solution at I = 0.20 mol dmm3 (LiCl) and the values at 25 "C of the rate constants (dm3 mol-' s-l) are ky = 1.71 and kNCs = 0.8 1 for the Ru(NH~)~~+ re