Electroabsorption spectroscopy of charge transfer states of transition metal complexes
โ Scribed by Bruce S. Brunschwig; Carol Creutz; Norman Sutin
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 212 KB
- Volume
- 177
- Category
- Article
- ISSN
- 0010-8545
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## Abstract For Abstract see ChemInform Abstract in Full Text.
## The charge transfer (CTLMJ spectra of octahedral transition metal compounds can be analyzed by using a simple model involving crystal field theory. It is shown that the metal and the ligand environment may be considered as two essentially separate, but weakly interacting entities. The charge tran
Chiroptical properties of chiral coordination compounds can be used to assign absolute configuration of ground and excited states. We discuss examples of transition metal complexes where MLCT, LMCT, MMCT and exciton LCT transitions have been observed. Such models are dimolybdenum complexes, cyclomet