✦ LIBER ✦

Charge transfer spectra of octahedral transition metal complexes

✍ Scribed by E. Verdonck; L.G. Vanquickenborne

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 790 KB
Volume: 23
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)94744-3

No coin nor oath required. For personal study only.

✦ Synopsis

The charge transfer (CTLMJ spectra of octahedral transition metal compounds can be analyzed by using a simple model involving crystal field theory. It is shown that the metal and the ligand environment may be considered as two essentially separate, but weakly interacting entities. The charge transfer spectra of a d" system can be treated by using crystal field theory of the corresponding d"+' systems.

The method described here was used in the analysis of tetrahedral transition metal complexes in a previous paper. It seems therefore to be of rather wide applicability in the field of transition metal chemistry.

📜 SIMILAR VOLUMES

Charge-Transfer Excited States of Transi

Charge-Transfer Excited States of Transition Metal Complexes

✍ John F. Endicott 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 23 KB 👁 1 views

Femtosecond Absorption Spectroscopy of T

Femtosecond Absorption Spectroscopy of Transition Metal Charge-Transfer Complexes

✍ James K. McCusker 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 48 KB 👁 1 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Charge-Transfer Spectra of Transition Me

Charge-Transfer Spectra of Transition Metal Ions in Silver Halides

✍ W. Ulrici 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB

Electroabsorption spectroscopy of charge

Electroabsorption spectroscopy of charge transfer states of transition metal complexes

✍ Bruce S. Brunschwig; Carol Creutz; Norman Sutin 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 212 KB

Trans-effects in octahedral transition m

Trans-effects in octahedral transition metal complexes

✍ Benjamin J Coe; Susan J Glenwright 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 901 KB

An extensive survey of the occurrences and origins of both structural trans-effects (STEs) and kinetic trans-effects (KTEs) in octahedral d-transition metal complexes is presented. This allows the identification of general STE classes into which the majority of common ligands fit: (a) very large STE

Molecular-orbital calculations on transi

Molecular-orbital calculations on transition-metal complexes: Charge-transfer transitions and the interpretation of photoelectron spectra

✍ W.Th.A.M. Van Der Lugt 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 391 KB

The results of some molecular-orbital caIculations on some transition-metal complexes according to a nove1 allvalence electron method are summarized. A comparison is made between the CalcuIated and experimental chargetransfer spectra. In addition, attention is drawn to the remarkable sequence of the