Electrical properties and crystal structures of MDSe-TTF and EDSe-TTF salts
β Scribed by Hatsumi Mori; Izumi Hirabayashi; Shoji Tanaka; Tekehiko Mori; Yusei Maruyama; Hiroo Inokuchi
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 375 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0038-1098
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Three new organic charge transfer salts formed by the organic donor bis(oxapropy1enedithio)tetrathiafulvalene (BOPDT-TTF or OTT) and CIO,, BrO, and Brl, anions have been synthesised. These crystals are semiconductors, adC(300 K) being equal to 0.12, 10 and ~x ~O -~S cm-' for the salts with CIO,, BrO
Additional work is in progress on characterization, physical properties and on varying the central metallic atom, and the size as well as the side chains of the azamacrocyclic ligand. ## Experimental The products were characterized by a combination of techniques. described in detail elsewhere [l6