Crystal structures and physical properties of cation radical salt (C1 TET-TTF)2PF6 and related salts
β Scribed by Akihiro Otsuka; Gunzi Saito; Tadashi Sugano; Minoru Kinoshita; Kazumasa Honda
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 359 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0040-6090
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Three new charge transfer salts of tetrathiafulvalene (TTF)based donors with selenocyanate-metal complex anions have been synthesized. The salts have been characterized as BEDT-TTF 4 [Cr(NCSe) 6 ] . CH 2 Cl 2 , II, TTF 3 [Cr(NCSe) 4 phen] 2 , III and BEDT-TTF 2 [Cr(NCSe) 4 phen] Γ CH 2 Cl 2 , IV, wh
Bromohexyl)-3Β’,4Β’-ethylenedioxy)-2,2Β’-bithiophene (3): Into a roundbottomed flask were introduced EDOT (5.9 g, 41.4 mmol) and 150 mL of tetrahydrofuran (THF). The mixture was cooled to Β±40 C and butyllithium, 2.5 M in hexanes (19 mL, 47.5 mmol), was added rapidly. After 1 h stirring, tributyltin chl