One of the primary scientific aims within the solid oxide fuel cell (SPOFC) community is to lower the operating temperature of an SOFC system from about 800-1,000 °C to intermediate temperatures of about 600 °C [1]. The lower operating temperature decreases thermal stress in the materials and offers
Electrical conductivity of epitaxial La0.6Sr0.4Co0.2Fe0.8O3−δ thin films grown by pulsed laser deposition
✍ Scribed by Ali Zomorrodian; Hadi Salamati; Zigui Lu; Xin Chen; Naijuan Wu; Alex Ignatiev
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 768 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0360-3199
No coin nor oath required. For personal study only.
✦ Synopsis
Epitaxial La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3Àd (LSCF) thin films have been grown successfully on single crystal LaAlO 3 substrate by pulsed laser deposition (PLD). AFM micrographs have shown a rms roughness of 5 A for the 550 C deposited films. The films further exhibited electrical conductivities of as high as 2.3 Â 10 3 S cm À1 at 600 C, with an activation energy of 0.09 eV.
The surface exchange coefficient (k chem ) of the epitaxial LSCF thin film, determined by electrical conductivity relaxation (ECR) technique, increased with the increasing temperature, and reached a value of w5.1 Â 10 À6 S cm À1 at temperatures above 620 C.
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## Abstract In this work, powders of La~0.6~Sr~0.4~Fe~0.8~Co~0.2~O~3–δ~ were prepared by the auto‐combustion of ethylene glycol–metal nitrate polymerised gel precursor. This method (polymeric organic complex solution) allows decreasing the processing temperature and simplifies the whole procedure.