Electrical and CO-sensing properties of SmFe0.7Co0.3O3 perovskite oxide
β Scribed by Ru Zhang; Jifan Hu; Ma Zhao; Zhouxiang Han; Jianying Wei; Zhanlei Wu; Hongwei Qin; Kaiying Wang
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 313 KB
- Volume
- 171
- Category
- Article
- ISSN
- 0921-5107
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β¦ Synopsis
In this work, nanocrystalline powders of perovskite-type compounds SmFe 1-x Co x O 3 (x = 0, 0.3) were prepared by sol-gel method. The morphology, electrical and carbon monoxide (CO) sensing properties of the nanocrystalline powders were studied by X-ray diffraction technique, Scanning Electron Microscopy (SEM), and electrical resistance measurements from 40 to 400 β’ C. The optimal value of CO-sensing response (S = R g /R a , here R a = resistances in atmospheric air with humidity = 45%, R g = resistances in CO within the background of atmospheric air with humidity = 45%) for nanocrystalline SmFe 0.7 Co 0.3 O 3 -based sensor is about 8.43 at 150 β’ C as the CO concentration is equal to 500 ppm. In addition, the SmFe 0.7 Co 0.3 O 3 sample shows a good selectivity to the gas CO.
π SIMILAR VOLUMES
In this paper we report the study of the perovskites La 0.7 Ca 0.3 Mn 0.5 Co 0.5 O 3 and La 0.8 Sr 0.2 Mn 0.5 Co 0.5 O 3 by neutron powder diffraction at various temperatures and magnetization measurements in zero applied field and at low cooling regimes. The replacement of half Mn by Co in La 0.7 C
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## Abstract The transient behaviour caused by the change of the component concentration for CO oxidation on the perovskiteβtype catalyst La~0.4~Sr~0.6~Co~0.4~Mn~0.6~O~3~ was investigated. Results showed that CO was not adsorbed on the catalyst surface and CO oxidation was carried out between the su