Electric moments and polarizabilities for LiH (X1Σ+)
✍ Scribed by George Maroulis; David M. Bishop
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 495 KB
- Volume
- 69
- Category
- Article
- ISSN
- 1432-2234
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## Abstract We use a variation–perturbation method to calculate the electric polarizabilities and the electric dipole moment of the LiH molecule. We obtain 4.455 for the perpendicular polarizability and 4.001 (×10^−24^ cm^3^) for the parallel polarizability. Our result for the electric dipole momen
The spin-caupled VB Theory is applied to the dipole moment function p(R) 01 LiH(X'Z\*) A series of calculations is reponed (1.7%. 127 and 188 spatial contigurauons) wluch demonslrates tie rapid convergence of thus properly onto thal given by aaurate MO CI wavefuncrions. The binding is essentially du
Electronic moments are given for internuclear distances, 0:5 6 R 6 50:0 bohr, for transitions connecting the six lowest 1 R þ u states and the 1 R þ g ground state of the hydrogen molecule. Except for the two lowest transitions, the computed moments show-due to avoided crossings-very strong R-depend