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1Σu+→X1Σg+ transition moments for the hydrogen molecule

✍ Scribed by L. Wolniewicz; G. Staszewska

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
136 KB
Volume
217
Category
Article
ISSN
0022-2852

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✦ Synopsis

Electronic moments are given for internuclear distances, 0:5 6 R 6 50:0 bohr, for transitions connecting the six lowest 1 R þ u states and the 1 R þ g ground state of the hydrogen molecule. Except for the two lowest transitions, the computed moments show-due to avoided crossings-very strong R-dependence; especially at R below 0.7 bohr. This effect is also clearly visible in the adiabatic corrections that are computed for 0:5 6 R 6 0:8.

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