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Electric dipole intensity parameters for lanthanide 4f → 4f transitions

✍ Scribed by Reid, Michael F.; Richardson, F. S.


Book ID
120286617
Publisher
American Institute of Physics
Year
1983
Tongue
English
Weight
911 KB
Volume
79
Category
Article
ISSN
0021-9606

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On the calculation of electric dipole st
✍ Frederick S. Richardson 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 284 KB

Electric dipole strengths calculated with the combined static coupling (SC)/dynamic coupling (DC) intensity model for 4f ~ 4f transitions in lanthanide complexes contain SC/DC cross-term ("interference") contributions which may add to or subtract from the purely static and dynamic contributions. Cal

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A) psramcteriration scl~eme of the Judd-Of& 4f-4f intensity model is shown to be inndcclwtc for rcprcscnting cffccts due to optically atriwtropic lignnd dipotw polarizations. "Estn" intensity parameters we nwdcd whm the kmtkmidc-ligmd painvise interactions arc not cylindrically syntntctric. Sclcctio