Anisotropic ligand polarizability contributions to lanthanide 4f → 4f intensity parameters

✍ Scribed by Michael F. Reid; Frederick S. Richardson

• Book ID: 103022445
• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 503 KB
• Volume: 95
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(83)80341-8

✦ Synopsis

A) psramcteriration scl~eme of the Judd-Of& 4f-4f intensity model is shown to be inndcclwtc for rcprcscnting cffccts due to optically atriwtropic lignnd dipotw polarizations. "Estn" intensity parameters we nwdcd whm the kmtkmidc-ligmd painvise interactions arc not cylindrically syntntctric. Sclcctiott rules rqsrdiug these "extra" pxz~mctcrs arc dcrivcd. aud their possible sigttifkutcc to tltc ltypsrsensitivity pltcnoutcuon is discuss~ti.