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Electric birefringence measurements in aqueous polyelectrolyte solutions

✍ Scribed by Kraemer, U.; Hoffmann, H.


Book ID
120351229
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
975 KB
Volume
24
Category
Article
ISSN
0024-9297

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## Abstract Four different fluoride, chloride, bromide, and nitrate cationic polyelectrolytes were prepared. Their electrolytic conductivity in aqueous dilute solution was investigated. The results show a remarkable increase, with dilution being practically constant down to limiting concentration.

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Electric birefringence (EB) in solutions of a series of fractions of polybutylisocyanate (PBIC) in tetrachloromethane in the range of molecular weights (M) from 5 x 103 to 8 Γ— 105 was investigated by using sinusoidal and rectangular pulse fields. Dispersion relaxation times (z) were determined from