## Abstract By a new procedure the resolution of DL‐3.4‐dihydroxyphenyl‐alanine into its optical antipodes is effected in good yield by means of fractional crystallization of the cinchonine salts of DL‐β‐(3‐hydroxy‐4‐methoxyphenyl)‐α‐benzoylaminopropionic acid. The well crystallized methylester‐hyd
Eine neue Spaltung von Dl-Threonin in die optischen Antipoden
✍ Scribed by K. Vogler; P. Lanz
- Publisher
- John Wiley and Sons
- Year
- 1959
- Tongue
- German
- Weight
- 310 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
A new resolution of DL‐threonine into the optical antipodes is effected by fractional crystallization of the stereoisomeric brucine salts of L‐ and D‐N‐phthaloyl‐threonine in methyl‐cellosolve. The two salts mentioned posses extraordinarily different degrees of solubility in methyl‐cellosolve, and this allows the production of D‐ and L‐threonine by simple operations in very high yield.
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