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Ein Zinn(II)-phosphat mit einer offenen Gerüst-struktur: [H3N(CH2)2NH3]0.52+ [Sn4P3O12]

✍ Scribed by Dr. Srinivasan Natarajan; Dr. Martin P. Attfield; Prof. Dr. Anthony K. Cheetham

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
550 KB
Volume
109
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

[H3N(CH2)2NH3][Sn4P3O12]−: An Open-Frame
[H3N(CH2)2NH3][Sn4P3O12]−: An Open-Framework Tin(II) Phosphate
✍ Dr. Srinivasan Natarajan; Dr. Martin P. Attfield; Prof. Anthony K. Cheetham 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 372 KB 👁 1 views

enforce an increase in the charge separation. However, whether an 0x0 ligand is sufficiently voluminous to have this steric effect is debatable, and calculations are currently underway to resolve this question." ' 1 Although the greater thermodynamic stability of the trans alcohol with respect to th

Synthesis and Structure of a New Open-Fr
Synthesis and Structure of a New Open-Framework Tin(II) Phosphate, [NH3CH2CH(NH3)CH3]0.5[Sn4P3O12]·H2O, Possessing One-Dimensional Channels
✍ Srinivasan Natarajan 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 393 KB

A new tin(II) phosphate, [NH 3 CH 2 CH(NH 3 )CH 3 ] 0.5 [Sn 4 P 3 O 12 ] ' H 2 O, was synthesized by hydrothermal technique. It crystallizes in monoclinic space group P2 1 /c (No. 14) with lattice parameters a ‫؍‬ 7.326(1) A s , b ‫؍‬ 23.614(3) A s , c ‫؍‬ 9.081(1) A s , ‫؍‬ 102.8(1)3, V ‫؍‬ 1532.1(